Process for the manufacture of alkyl ketene dimers by...

C - Chemistry – Metallurgy – 07 – D

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C07D 305/12 (2006.01) C07C 45/89 (2006.01) C07C 49/88 (2006.01)

Patent

CA 2119997

A process is disclosed for the synthesis of alkyl ketene dimers by the dehydrohalogenation of a C8 - C22 saturated or unsaturated linear fatty acid halide, comprising reacting the fatty acid chloride with a cyclic tertiary amine in an inert solvent at a temperature of up to 75°, separating tertiary amine hydrochloride salts from alkyl ketene dimer dissolved in the solvent, and recovering the alkyl ketene dimer from the solvent.

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