Process for the manufacture of .alpha.,.alpha.-branched...

C - Chemistry – Metallurgy – 07 – C

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C07C 51/10 (2006.01) C07C 51/12 (2006.01) C07C 51/14 (2006.01) C07C 53/128 (2006.01)

Patent

CA 2347756

A process for manufacture of .alpha.,.alpha.-branched carboxylic acids from linear olefins by means of reaction with carbon monoxide and an acid catalyst, characterized in that a linear olefin containing from 2 to 5 carbon atoms, or a precursor thereof, is reacted in a batch reactor or a continuous reactor, with carbon monoxide and water, in the presence of a catalyst having sufficient acid groups to provide requisite protons for the formation of Koch acid, and in the presence of a polar non- coordinating organic solvent.

L'invention concerne un procédé de production d'acides alpha , alpha carboxyliques ramifiés à partir d'oléfines linéaires au moyen d'une réaction effectuée avec le monoxyde de carbone et un catalyseur acide. Ledit procédé se caractérise par le fait que l'on fait réagir une oléfine linéaire contenant 2 à 5 atomes de carbone, ou un de ses précurseurs, dans un réacteur discontinu ou un réacteur continu avec du monoxyde de carbone et de l'eau, en présence d'un catalyseur ayant suffisamment de groupes acides pour fournir les protons nécessaires à la formation de l'acide de Koch, et en présence d'un solvant organique non coordinateur polaire.

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