Process for the manufacture of chloroform

Details Process for the manufacture of chloroform Process for the manufacture of chloroform

C - Chemistry, Metallurgy

07

C

C07C 17/00 (2006.01) B01J 23/40 (2006.01) C07C 19/04 (2006.01)

Patent

CA 2046892

A process for the manufacture of chloroform by catalytic hydrogenolysis of carbon tetrachloride in liquid phase, wherein liquid phase carbon tetrachloride is reacted with hydrogen gas or a gas containing molecular hydrogen, at a pressure below 8,000 kPa and at a temperature below 250°C, in the presence of a catalyst formed by a metal selected from the group formed by palladium, rhodium, ruthenium and platinum, deposited on a substrate and held in suspension in the liquid. It is applicable in the industrial preparation of chloro- form from carbon tetrachloride.

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