Process for the manufacture of homo-and copolymers of...

C - Chemistry – Metallurgy – 08 – F

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C08F 14/18 (2006.01) C08F 14/26 (2006.01)

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CA 1073147

HOE 75/F 905 PROCESS FOR THE MANUFACTURE OF HOMO- AND COPOLYMERS OF TETRAFLUORETHYLENE ABSTRACT OF THE DISCLOSURE Polymers on the basis of tatrafluoroethylene are produced in the pre- sence of a redox system as catalyst consisting of a usual peroxidic compound as oxidizing component and a water-soluble nitrogen compound liberating in situ a diimine under the polymerization conditions. The polymers obtained can be processed, inter alia, into thick walled articles on a ram extruder or into large sintered block free from crack formation.

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