C - Chemistry – Metallurgy – 01 – B
Patent
C - Chemistry, Metallurgy
01
B
C01B 33/12 (2006.01) C01B 33/193 (2006.01)
Patent
CA 2114665
ABSTRACT OF THE DISCLOSURE A process for the manufacture of pure amorphous silica from rocks containing non-crystalline silica is described. The process comprises the steps of: (a) dissolution of said rock in an alkaline solution com- prising sodium hydroxide and sodium carbonate, obtaining a solution of sodium silicate; (b) precipitation of pure amorphous silica by adding sodium bicarbonate into said sodium silicate and co-producing sodium carbonate, the weight ratio between SiO2 and Na2O in said dissolution step is in the range of between 0.5 to 3.0; and (c) the sodium carbonate solution is transformed into crystalline sodium bicarbonate, by a salting out reaction with sodium chloride, being recycled to the process. According to a preferred embodiment, the alkaline solution is obtained by the caustification of sodium carbonate with calcium hydroxide. The preferred concentration of sodium hydroxi- de in said dissolution step is in the range of 4% to 14% by weight.
Rotem Amfert Negev Ltd.
Sim & Mcburney
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