Process for the monoepoxidation of compounds containing two...

Details Process for the monoepoxidation of compounds containing two... Process for the monoepoxidation of compounds containing two...

C - Chemistry, Metallurgy

07

D

260/369

C07D 301/12 (2006.01) B01J 29/89 (2006.01) C07D 303/04 (2006.01) C07D 303/16 (2006.01) C07D 303/22 (2006.01)

Patent

CA 1265810

"PROCESS FOR THE MONOEPOXIDATION OF COMPOUNDS CONTAINING TWO DOUBLE BONDS" Abstract The invention relates to a process for the monoep- oxidation of compounds containing two olephinic double bonds by means of hydrogen peroxide in the presence of a catalyst constituted by a Si-Ti synthetic zeolite (tita- nium-silicalite), wherein Ti and Si in the form of their oxides TiO2 and SiO2 have a molar ratio in the zeolite corresponding to the formula x TiO2 . (1-x) SiO2 with x being comprised within the range of from 0.0001 to 0.04, preferably of from 0.0055 to 0.036, possibly in the presence of at least one solvent of polar nature, by operating with the heterogeneous catalyst being dis- persed in the liquid phase at a temperature of from 0°C to 150°C, and under a pressure comprised within the range of from 0.1 abs.atm to 20 abs.atm.

501087

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