Process for the oxidation of organic compounds in the...

C - Chemistry – Metallurgy – 07 – D

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C07D 303/04 (2006.01) B01J 31/18 (2006.01) C07C 29/48 (2006.01) C07C 33/46 (2006.01) C07C 45/28 (2006.01) C07C 47/54 (2006.01) C07D 301/03 (2006.01) C07D 301/12 (2006.01) C07D 303/08 (2006.01)

Patent

CA 2194340

Disclosed and claimed are oxidation reactions involving, as a catalyst, a bis- and/or tris-(µ-oxo)-dimanganese complex salt of the formula I [LMn(µ-O) a (µ-OAc) bMnL]XAy (I) Ac is a C2-C8-acyl group, a is 1, 2 or 3, b is 0 when a is 2 or 3 or b is 2 when a is 1, x indicates the number of positive charges and is 2 or 3, A is a singly or doubly negatively charged anion, y is the number of anions A required to balance the positive charges and L is a ligand, such as N,N-bis(2-pyridylmethyl)-N- methylamine or N,N,N',N'-tetrakis(2-pyridyl(methyl)-N- methylamine or N1 N1 N1, N1-tetrakis(2-pyridylmethyl)- 1,2-ethylenediamine.

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