Process for the oxidation of primary allylic and benzylic...

Details Process for the oxidation of primary allylic and benzylic... Process for the oxidation of primary allylic and benzylic...

C - Chemistry, Metallurgy

07

C

260/565, 260/367

C07C 45/26 (2006.01) C07C 47/20 (2006.01) C07C 47/45 (2006.01) C07C 47/54 (2006.01) C07D 307/44 (2006.01)

Patent

CA 1067505

ABSTRACT OF THE DISCLOSURE Improved conversions of primary allylic and benzylic alcohols are obtained in an Oppenauer oxidation process, under Oppenauer oxidation conditions, by carrying out the oxidation employing furfural as the hydrogen acceptor. Primary alcohols to which the present invention relates are: allylic alcohols substituted in at least the 2-position with a hydrocarbon radical; and benzylic alcohols.

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