Process for the polymerization of cyclic olefins and a...

C - Chemistry – Metallurgy – 08 – G

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C08G 61/00 (2006.01) G03F 7/028 (2006.01)

Patent

CA 2168134

Process for the polymerization of cyclic olefins by photochemical ring-opening metathesis polymerization by irradiation, using catalytic amounts of a heat-stable ruthenium or osmium catalyst which has at least one photolabile ligand, the other coordination sites being occupied by non-photolabile ligands.

Procédé de polymérisation d'oléfines cycliques au moyen de la polymérisation photochimique à métathèse et à ouverture de cycle, effectuée par irradiation, consistant à utiliser des quantités catalytiques d'un catalyseur à base de ruthénium ou d'osmium à stabilité thermique comprenant au moins un ligand photolabile, les autres sites de coordination étant occupés par des ligands non photolabiles.

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