Process for the polymerization of olefins; novel...

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01) C08F 210/16 (2006.01)

Patent

CA 2314140

A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provided is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.

Ce nouveau procédé de polymérisation d'oléfines consiste à mettre au moins une oléfine en contact avec un catalyseur du type Ziegler-Natta en présence d'un composé précis, ce qui donne des produits polymères à répartition plus étroite du poids moléculaire. L'invention concerne également un procédé permettant de rendre plus étroite la répartition du poids moléculaire d'une polyoléfine, lequel procédé consiste à mettre en contact une oléfine, un catalyseur Ziegler-Natta et un composé précisé dans le descriptif. Elle porte, de surcroît, sur de nouveaux polyéthylènes ainsi que sur des films et des articles produits à l'aide de ceux-ci.

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