Process for the preparation of 1,1-dihalo-4-methyl-1,...

C - Chemistry – Metallurgy – 07 – C

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260/659, 260/631

C07C 69/74 (2006.01) C07C 1/24 (2006.01) C07C 17/00 (2006.01) C07C 29/143 (2006.01)

Patent

CA 1107300

ABSTRACT: Novel processes for the preparation of 1,1-dihalo-4- methyl-1,3-pentadienes, key intermediates in the synthesis of dihalovinylcyclopropanecarboxylates, are described. The processes begin with the condensation of a vinylidene halide and an isobutyryl halide in the presence of a Lewis acid catalyst, followed by reduction of the 1,1-dihalo-4-methyl- 1-penten-3-one produced thereby, and dehydration of the resulting 1,1-dihalo-3-hydroxy-4-methyl-1-pentene.

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