Process for the preparation of 3,3-dimethyl- allyl alcohol

C - Chemistry – Metallurgy – 07 – C

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260/631.7

C07C 33/03 (2006.01) C07C 29/09 (2006.01)

Patent

CA 1139788

ABSTRACT OF THE DISCLOSURE The present invention concerns a process for the preparation of 3,3-dimethyl-allyl alcohol. In said process a 3,3-dimethyl-allyl halide is reacted with an alkaline carboxylate and the 3,3-dimethyl-allyl carboxylate thus obtained is hydrolyzed by treatment with an alkaline hydroxide. Both reactions are carried out in a two-phase system, in the presence of a phase-transfer catalyst. The 3,3-dimethyl- allyl alcohol is obtained in high yields without by-products due to isomerization reactions.

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