C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
260/248.6
C07D 253/06 (2006.01) C07D 253/07 (2006.01) C07D 405/04 (2006.01) C07D 409/04 (2006.01)
Patent
CA 1180014
ABSTRACT Process for the preparation of 3,6-di- substituted 4-amino-1,2,4-triazin-5-ones The herbicidal 3,6-substituted 4-amino-1,2,4- triazin-5-one of the general formula Image (I) wherein R1 and R2 have the meaning given in the description, is obtained in good yields by a new two-stage cyclis- ation reaction if an .alpha.-ketocarboxylic acid amide of the general formula R1-CO-CO-NHR3 (II) is reacted with a hydrazidine of the general formula Image (III) if appropriate in the presence of a diluent at tempera- tures between 0 and 150°C, whereby in the first process stage a condensation reaction takes place to give con- densation products which still have open chains, and in the second process stage an elimination reaction with ring closure takes place to give the end product of formula (I).
394706
Blank Heinz U.
Bonse Gerhard
Marzolph Gerhard
Schmidt Thomas
Timmler Helmut
Aktiengesellschaft Bayer
Fetherstonhaugh & Co.
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