Process for the preparation of 4-alkoxyaceto-acetic acid esters

C - Chemistry – Metallurgy – 07 – C

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31/1, 260/488.1

C07C 69/716 (2006.01) C07C 69/72 (2006.01)

Patent

CA 1187509

ABSTRACT OF THE DISCLOSURE Process for the production of 4-alkoxyacetoacetic acid esters from 4-chloro- or 4-bromoacetoacetic esters. The 4-chloro- or 4-bromoacetoacetic ester is reacted with a highly concentrated solution of an alkali alcoholate in alcohol having been concentrated at elevated temperatures, at temperatures of 50° to 120°C. At least 2.8 mole of the alkali alcoholate are used per mole of 4-chloro- or 4-bromo- acetoacetic ester.

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