Process for the preparation of 5-hydroxymethylthiazoles

C - Chemistry – Metallurgy – 07 – D

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C07D 277/24 (2006.01) C07D 277/22 (2006.01) C07D 277/32 (2006.01)

Patent

CA 2294089

The present invention discloses a process for the preparation of a hydroxymethylthiazole compound having formula (3). The process of the invention comprises reacting a halomethyl thiazole having formula (A) with water, at an elevated temperature. Optionally, the reaction can be carried out in the presence of a base, such as sodium carbonate, which can react with any acid formed. In the process of the invention, X is a halogen atom; and R6 is selected from the group consisting of hydrogen, and halogen atoms. The invention also contemplates the preparation of acid addition salts of the hydroxymethylthiazole, compound (3).

La présente invention porte sur un procédé de préparation d'un composé hydroxyméthylthiazole ayant la formule (3). Ce procédé consiste à faire réagir un halométhyle thiazole ayant la formule (A) avec de l'eau, à température élevée. La réaction peut éventuellement être réalisée en présence d'une base telle que le carbonate de sodium qui peut réagir avec tout acide produit. Selon cette invention, X représente un atome d'halogène, et R?6¿ est sélectionné dans le groupe constitué par hydrogène et des atomes d'halogène. L'invention porte également sur la préparation de sels d'addition acides du composé hydroxyméthylthiazole (formule (3)).

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