Process for the preparation of 5-nitro-1,4-naphthoquinone

C - Chemistry – Metallurgy – 07 – C

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260/396, 204/43.

C07C 201/12 (2006.01) C07C 205/46 (2006.01) C25B 3/02 (2006.01)

Patent

CA 1284650

Process for the preparation of 5-nitro-1,4-naphthoquinone Abstract of the Disclosure A process for the preparation of 5-nitro-1,4-naphthoquinones of formula Image wherein R is hydrogen, a C1-C4alkyl radical or a C1-C4alkoxy radical, by oxidation of 1-nitronaphthalene or a suitably substi- tuted 1-nitronaphthalene, which process comprises carrying out the reaction with manganese(III) sulfate as oxidising agent. The manganese(III) sulfate consumed can be regenerated electro- lytically with good current yield. The process is environmentally safe, as the oxidising agent and the solvent, if any, can be reused.

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