Process for the preparation of a high purity cobalt...

C - Chemistry – Metallurgy – 22 – B

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C22B 3/42 (2006.01) C22B 3/26 (2006.01) C22B 23/00 (2006.01)

Patent

CA 2134490

A process for the preparation and purification of a cobalt intermediate from a cobalt sulphate solution containing cationic and anionic impurities, including the successive steps of: (i) reacting the cobalt sulphate solution with an organic reagent to extract unwanted cationic impurities from the sulphate solution; (ii) extracting the cobalt from the sulphate solution with an organic reagent, to create a cobalt loaded organic phase substantially free of all anionic impurities; (iii) stripping the cobalt loaded organic phase with a high strength ammoniacal ammonium carbonate solution, to create an ammoniacal ammonium carbonate strip liquor rich in cobalt II ammines; (iv) converting the cobalt II ammines to cobalt III tetrammines; (v) extracting the majority of nickel from the cobalt rich ammoniacal liquor with a suitable organic reagent; and (vi) recovering the cobalt from the cobalt rich ammoniacal liquor.

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