Process for the preparation of an ethylenically unsaturated...

C - Chemistry – Metallurgy – 07 – C

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260/481.4

C07C 69/54 (2006.01) C07C 67/08 (2006.01) C08G 63/46 (2006.01)

Patent

CA 1089874

ABSTRACT OF THE DISCLOSURE The present invention provides a process for the preparation of an ethylenically unsaturated ester, which process comprises reacting at least one of acrylic acid and methacrylic acid with a hydroxy compound having at least one primary hydroxyl group in the presence of an acid esterification catalyst and a water-immiscible organic solvent, the improvement which comprises adding at conclusion of the esterification reaction a lithium compound to the esterification mixture, which is subsequently subjected to distillation.

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