Process for the preparation of an organo-substituted sodium...

C - Chemistry – Metallurgy – 07 – F

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260/367, 260/433

C07F 5/06 (2006.01)

Patent

CA 2003848

ABSTRACT OF THE DISCLOSURE A process is provided herein for preparing an organo- substituted sodium aluminum hydride. Such organo- substituted sodium aluminum hydride is represented by the formula: NaAlHXZ4-x wherein X is an integer of 1 to 3, and Z is an organic group obtained by eliminating an active hydrogen atom from (1) an alcohol or a phenol; (2) a tetrahydrofurfuryl alcohol; (3) an ether alcohol obtained by alkylating one hydroxyl group of a diol; (4) a polyether alcohol obtained by condensation of an ether alcohol and diol so as to remove one mole of water; (5) a tetrahydropyranyl alcohol; or (6) a compound having the formula: (R)2=N(-CH2)nOH wherein R is the same or different and is selected from the group consisting of an alkyl group having from 1 to 4 carbon atoms, an alkoxy alkyl group and an aryl group having from 6 to 8 carbon atoms and n is an integer of 2 to 4. The process comprises reacting, in a solvent therefor, an organic compound as described above with a sodium, hydrogen, and aluminum which is in the form of an alloy containing an element belonging to Group IVa or Group Va of the Periodic Table.

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