Process for the preparation of an oxirane compound

C - Chemistry – Metallurgy – 07 – D

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260/372.3

C07D 301/19 (2006.01) B01J 21/06 (2006.01) C07D 303/04 (2006.01)

Patent

CA 1327206

A B S T R A C T A PROCESS FOR THE PREPARATION OF AN OXIRANE COMPOUND The invention relates to a process for the preparation of an oxirane compound by reacting an olefinic compound with an organic hydroperoxide by the use of a heterogeneous catalyst, which is essentially insoluble in the reaction mixture, said catalyst comprising, titanium in chemical combination with a solid silica and/or inorganic silicate characterized in that a catalyst is used obtainable by a) impregnating the silicium compound with a stream of gaseous titanium tetrachloride, b) calcining the obtained reaction product of step a), and c) hydrolysis of the product of step b).

601302

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