Process for the preparation of c5 and/or c6 olefins

Details Process for the preparation of c5 and/or c6 olefins Process for the preparation of c5 and/or c6 olefins

C - Chemistry, Metallurgy

07

C

C07C 2/86 (2006.01) C07C 11/10 (2006.01) C07C 11/107 (2006.01)

Patent

CA 2650618

Process for the preparation of C5 and/or C6 olefins from a lower olefin, which lower olefin comprises from 2 to 5 carbon atoms, and an oxygenate, which oxygenate comprises at least one oxygen-bonded alkyl group, comprising contacting the lower olefin with the oxygenate, in a molar ratio of oxygen-bonded alkyl group to lower olefin of at least 1:1 in the presence of a MTT-type zeolite.

L'invention concerne un procédé de préparation d'oléfines C5 et/ou C6 à partir d'une oléfine inférieure, laquelle comprend entre 2 et 5 atomes de carbone, et d'un composé oxygéné qui comprend au moins un groupe alkyle lié à un atome d'oxygène. Le procédé consiste à mettre en contact l'oléfine inférieure avec le composé oxygéné, selon un rapport molaire groupe(s) alkyle lié(s) à un atome d'hydrogène/oléfine inférieure d'au moins 1:1, en présence d'une zéolithe du type MTT.

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