Process for the preparation of ceric hydrocarbyl silyloxides...

Details Process for the preparation of ceric hydrocarbyl silyloxides... Process for the preparation of ceric hydrocarbyl silyloxides...

C - Chemistry, Metallurgy

07

F

260/426.2, 260/4

C07F 7/08 (2006.01)

Patent

CA 1310016

PROCESS FOR THE PREPARATION OF CERIC HYDROCARBYL SILYLOXIDES BY TRANSETHERIFICATION OF CERIC ALKOXIDES ABSTRACT OF THE DISCLOSURE A process is provided for preparing ceric hydrocarbyl silyloxides, which comprises transetherifying a ceric alkoxide with the silanol having the desired hydrocarbyl group and the desired number of hydroxyl groups under anhydrous conditions at a temperature within the range from about -30°C to about 200°C, thereby displacing the aliphatic alcohol of the alkoxide and forming the ceric hydrocarbyl silyloxide of the silanol,

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