Process for the preparation of chiral beta amino acid...

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 209/52 (2006.01) B01J 31/24 (2006.01) C07D 241/00 (2006.01) C07D 249/00 (2006.01) C07D 487/04 (2006.01) C07F 17/02 (2006.01)

Patent

CA 2518435

The present invention relates to a process for the efficient preparation of enantiomerically enriched beta amino acid derivatives which are useful in the asymmetric synthesis of biologically active molecules. The process comprises an enantioselective hydrogenation of a prochiral beta amino acrylic acid derivative substrate in the presence of a transition metal precursor complexed with a chiral ferrocenyl diphosphine ligand.

La présente invention concerne un procédé pour préparer efficacement des dérivés d'acide aminé béta enrichis en énantiomères, utilisés dans la synthèse asymétrique de molécules biologiquement actives. Ce procédé consiste en une hydrogénation énantiosélective d'un substrat de dérivé d'acide aminoacrylique béta prochiral en présence d'un précurseur de métal de transition complexé avec un ligand de diphosphine de ferrocényle chiral.

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