Process for the preparation of dialkyl oxalates

C - Chemistry – Metallurgy – 07 – C

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260/486.7

C07C 69/36 (2006.01)

Patent

CA 1093580

ABSTRACT OF THE DISCLOSURE A process for the preparation of dialkyl oxalates by reacting an aliphatic alcohol with carbon monoxide under pressure, which comprises carrying out the reaction in the presence of (a) a catalyst comprising a platinum group metal or a salt thereof, and (b) an accelerator composed of one or more compounds selected from the group consisting of nitric acid and nitrogen oxides.

283465

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