Process for the preparation of diamines of the...

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260/597.8

B01J 31/10 (2006.01)

Patent

CA 1210410

ABSTRACT An improved process for the preparation of diamines of the diphenylmethane series by condensing arylamines in which the para-position relative to the amino group is free, with formaldehyde, followed by rearrangement at elevated tempera- ture, a copolymer of tetrafluoroethylene and perfluorovinyl ethers being used as a heterogeneous acid catalyst. By means of this process the content of polynuclear polyamines with three or more nuclei, in the reaction product, can be re- duced to less than 5% by weight.

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