Process for the preparation of esters directly from alcohols

Details Process for the preparation of esters directly from alcohols Process for the preparation of esters directly from alcohols

C - Chemistry, Metallurgy

07

C

260/479.1, 260/4

C07C 67/08 (2006.01) C07C 67/40 (2006.01) C07C 69/24 (2006.01)

Patent

CA 1321209

ABSTRACT OF THE DISCLOSURE Esters are prepared directly from 2-substituted alcohols, such as Guerbet alcohols, by dehydrogenating and esterifying the alcohol at 170°C-240°C in the presence of a catalyst system comprising (1) platinum on activated carbon, zinc oxide or zinc C2-C20 carboxylate and (ii) NaOH, KOH or LiOH. Mixed esters may also be prepared from appropriate mixtures of 2-substituted alcohols.

571595

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