Process for the preparation of fluid bed vinyl acetate catalyst

B - Operations – Transporting – 01 – J

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B01J 23/56 (2006.01) B01J 23/52 (2006.01) B01J 23/58 (2006.01) B01J 32/00 (2006.01) B01J 35/10 (2006.01) B01J 37/00 (2006.01) B01J 37/02 (2006.01) C07C 67/055 (2006.01) C07C 69/15 (2006.01) B01J 21/08 (2006.01) B01J 23/44 (2006.01)

Patent

CA 2143042

A process for the preparation of a fluid bed vinyl acetate (VAM) catalyst comprising impregnating a support comprising a mixture of substantially inert microspheroidal particles with a solution comprising a halide-free metal salt of Pd and M, wherein M comprises Ba, Au, La, Nb, Ce, Zn, Pb, Ca, Sr, Sb or mixtures thereof, reducing the metal salts to form a deposit of Pd and M on the support surface and impregnating the support with at least one halide-free alkali metal salt. At least 50% of the particles used for the microspheroidal support have a particle size below 100 microns, preferably below 60 microns.

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