C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
C07D 301/28 (2006.01) C07D 303/20 (2006.01) C07D 303/22 (2006.01) C07D 303/24 (2006.01)
Patent
CA 2057737
K-18466/A Improved process for the preparation of glycidyl ethers Abstract of the Disclosure An improved process for the preparation of glycidyl ethers of formula I Image (I), wherein Q is an aliphatic, cycloaliphatic or araliphatic radical of valency m, R is -H or -CH3, and m is an integer from 1 to 10, by reacting an alcohol of formula Q-(OH)m with m mol of an epihalohydrin of formula II Image (II) in the presence of a catalyst to the corresponding halohydrin ether, and dehydrohalogenating said halohydrin ether with an alkali metal hydroxide to give a compound of formula I, wherein Q, m and R are as defined above and Hal is halogen, which process comprises using as catalyst a) tin difluoride or b) a divalent tin halide in conjunction with a co-catalyst.
Roth Martin
Truffer Marc-Andre
Wolleb Heinz
Ag Ciba-Geigy
Fetherstonhaugh & Co.
Roth Martin
Truffer Marc-Andre
Wolleb Heinz
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