Process for the preparation of glycosides from glycosyl...

Details Process for the preparation of glycosides from glycosyl... Process for the preparation of glycosides from glycosyl...

C - Chemistry, Metallurgy

07

H

260/227

C07H 3/00 (2006.01) C07H 7/033 (2006.01) C07H 9/04 (2006.01) C07H 15/04 (2006.01)

Patent

CA 1258852

ABSTRACT OF THE INVENTION A process for the manufacture of glycosides which comprises reacting a protected hexopyranosyl fluoride with an aglycon or a silyl ether thereof in the presence of a metal fluoride of group IV or V of the periodic table, said metal having an atomic number of at least 22 and being present in the fluoride in a higher, stable and non-oxidizing or weakly oxidizing stage. The products of the process are useful as intermediates for a large number of syntheses, such as for the synthesis of oligo- or poly-saccharides which may represent important biological surface structures.

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