Process for the preparation of hydrocarbons

Details Process for the preparation of hydrocarbons Process for the preparation of hydrocarbons

C - Chemistry, Metallurgy

07

C

260/710, 260/709

C07C 1/04 (2006.01) C07C 9/00 (2006.01) C07C 11/02 (2006.01)

Patent

CA 2016619

\ T 5124 A B S T R A C T PROCESS FOR THE PREPARATION OF HYDROCARBONS The invention relates to a process for the preparation of hydrocarbons by catalytic reaction of carbon monoxide with hydrogen, comprising the steps of: a) selecting a catalyst comprising: i) 3-80 parts by weight cobalt per 100 parts by weight of porous carrier; ii) 0.1-100 parts by weight of at least one metal selected from zirconium, titanium and chromium, per 100 parts by weight of porous carrier; and iii) an external surface area (Se) Se < 70 cm2 /ml; b) activating the catalyst; and c) contacting the activated catalyst in a fixed bed form with a mixture of carbon monoxide and hydrogen having a hydrogen/- carbon monoxide feed ratio (F) F < 1.9 under such conditions that Se/F > 12 5, and to hydrocarbons obtained therewith. CS6/T5124

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