Process for the preparation of hydrocarbons

C - Chemistry – Metallurgy – 07 – C

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260/678.6

C07C 1/04 (2006.01) B01J 35/10 (2006.01)

Patent

CA 1095535

K 5383 A B S T R A C T Process for the preparation of hydrocarbons. A mixture of carbon monoxide and hydrogen, whose H2/CO molar ratio is less than 1.0, is contacted at elevated temperature and pressure with a combination of two catalysts. One catalyst is capable of converting at least 30 %m of the H2/CO mixture with a selectivity of at least 70 %w for C3+ hydrocarbons. The other catalyst is capable of converting at least 80 %m of the water present in a mixture of carbon monoxide and water having a CO/H2O molar ratio of 10.0 into hydrogen. At least 10 %v of each catalyst is present in the catalyst combination.

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