Process for the preparation of methyl carbamates

C - Chemistry – Metallurgy – 07 – D

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C07D 307/86 (2006.01) A01N 47/10 (2006.01) C07C 263/12 (2006.01) C07C 269/02 (2006.01) C07C 271/12 (2006.01) C07D 307/78 (2006.01) C07D 307/84 (2006.01) C07D 317/18 (2006.01) C07D 317/24 (2006.01) C07D 317/64 (2006.01)

Patent

CA 1247113

TITLE PROCESS FOR THE PREPARATION OF METHYL CARBAMATES Abstract of the Disclosure A continuous, close-coupled method for making N-methyl carbamate pesticides which comprises con- tacting the methyl isocyanate in a vapor phase mix- ture containing methyl isocyanate and water with a selected oxime or phenol, said mixture being the reaction product formed by oxidizing monomethylform- amide. An optional intermediate step for preparing the methyl isocyanate/water vapor phase reaction mix- ture for contact with the oxime or phenol is to remove therefrom a portion of the water without liquefying the methyl isocyanate by cooling the mixture to a temperature below the dew point of water but above the dew point of the methyl isocyanate.

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