Process for the preparation of optically active...

C - Chemistry – Metallurgy – 07 – C

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260/514.4, 260/5

C07C 59/66 (2006.01) C07C 51/353 (2006.01)

Patent

CA 1131249

ABSTRACT The invention relates to the preparation of optically active aryloxyalkanoic acid derivatives of the formula Image wherein Ar represents an optionally substituted phenyl or naphthyl radical, R represents an alkyl radical containing from 1 to 4 carbon atoms, and A represents a -COOR1 radical, by reacting an aqueous or aqueous- organic solution of an optically active alkali metal salt of a 2-halogenoalkanoic acid with an aqueous solution of an alkali metal salt of a phenol of the formula Ar-OH at an elevated temperature under a pressure lower than the vapour pressure of water at the reaction temperature: the aryloxyalkanoic acid derivatives having the D configuration are useful as herbicides.

355025

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