Process for the preparation of polyarylenesiloxanes by melt...

C - Chemistry – Metallurgy – 08 – G

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C08G 77/06 (2006.01) C08G 77/52 (2006.01) C08G 77/60 (2006.01)

Patent

CA 2084586

- 1 - HOE 91/F 381 Abstract: Process for the preparation of polyarylenesiloxanes by melt condensation of readily volatile silanes with high- melting bisphenols. Process for the preparation of polyarylenesiloxanes by melt condensation, in which difunctional silanes having a boiling point of ?130°C are reacted with bisphenols which have a melting point above 110°C, in the presence of a catalyst, at temperatures in the range from 35 to 200°C. Bisphenols of the formula II Image (II) and difunctional silanes of the formula (III) Image are preferably used. The catalysts used are aromatic or aliphatic amine compounds.

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