Process for the preparation of polyisocyanates containing...

C - Chemistry – Metallurgy – 08 – G

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402/133, 402/159

C08G 18/78 (2006.01) C07C 273/18 (2006.01) C08G 18/80 (2006.01) C07C 275/62 (2006.01)

Patent

CA 1133005

ABSTRACT OF THE DISCLOSURE A process for the preparation of polyisocyanates containing biuret and/or higher polyuret groups by reacting secondary diamines with diisocyanates characterized in that the reaction is carried out in the presence of catalytic quantities of strong acids which form mixed carbamic acid anhydrides with isocyanates. Alternatively the secondary diamines may be reacted with organic diisocyanates in the absence of catalysts to form a urea diisocyanate which is then reacted in the presence of catalytic quantities of strong acids which form mixed carbamic acid anhydrides either with the same diisocyanate used in the first step or a second diisocyanate. The invention also relates to the polyisocyanates containing biuret and/or higher poly- uret groups obtainable by this process.

342006

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