Process for the preparation of pyridine

C - Chemistry – Metallurgy – 07 – D

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260/294.7

C07D 213/12 (2006.01) C07D 213/06 (2006.01)

Patent

CA 1145754

- 1 - Abstract of the Disclosure Pyridine is prepared by ammoxidation (= reaction with oxygen or an oxygen-containing gas and ammonia, if appropriate in the presence of steam) of cyclopenta- diene in the presence of a tellurium-free silica gel ca- talyst, ?-A12O3 catalyst and/or aluminum silicate catalyst, which is preferably also doped with transition metal oxides and/or the oxides of gallium and/or indium and, if appropriate, also contains trivial quantities of further customary additives. The surface area of the catalyst should be between about 75 and 800 m2/g and the pore volume between about 0.2 and 2 cm3/g, and the reaction temperature should be between about 200 and 400°C. The pyridine formed in the process is free from picolines and higher homologs.

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