Process for the preparation of secondary monomethylalkyl amines

C - Chemistry – Metallurgy – 07 – C

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C07C 209/62 (2006.01) C07C 209/26 (2006.01) C07C 211/08 (2006.01) C07C 211/27 (2006.01)

Patent

CA 2060253

Abstract of the Disclosure A process for the preparation of a highly selective amount of secondary monomethylalkyl amine, said process comprising reacting, at elevated temperature and pressure, a hexahydrotriazine compound in the liquid state with hydrogen in the presence of a catalyst material having at least one catalytically active metal, said hexahydrotriazine compound having the formula Image wherein R1, R2, and R3 are, independently, straight or branched, saturated or unsaturated, linear or cyclic hydrocarbon groups or straight or branched, saturated or unsaturated, linear or cyclic hydrocarbon groups wherein one or more CH2 groups are replaced by an oxygen atom or a tertiary amine group, provided that any unsaturated group is separated from nitrogen in the hexahydrotriazine ring by at least one carbon atom, any said oxygen atom is enclosed by two carbon groups, and any said oxygen atoms and any said amine groups are separated from other oxygen atoms and other amine groups and from said nitrogen in the hexahydrotriazine ring by at least two carbon atoms.

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