Process for the preparation of styrene derivatives extended...

C - Chemistry – Metallurgy – 07 – C

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C07C 15/44 (2006.01) B01J 31/18 (2006.01) C07B 37/02 (2006.01) C07C 2/04 (2006.01) C07C 2/26 (2006.01) C07C 25/24 (2006.01) C07C 45/69 (2006.01) C07C 49/784 (2006.01) C07C 49/796 (2006.01) C07C 49/813 (2006.01) C08F 210/02 (2006.01) C08F 212/12 (2006.01)

Patent

CA 2043798

The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20 to 160°C and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula Image in which R19 denotes hydrogen, C1-C4,-alkyl, vinyl or chlorine and R38 denotes C1-C4-alkyl, C2-C4-alkenyl, C2-C7-acyl, fluorine, chlorine or bromine and m assumes values of 4-104, with the exception of compounds wherein R19 denotes hydrogen and R38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.

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