Process for the preparation of substituted amido...

C - Chemistry – Metallurgy – 09 – B

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C09B 47/26 (2006.01) C07D 209/00 (2006.01) C07D 259/00 (2006.01) C07D 487/22 (2006.01)

Patent

CA 2340129

A process for the preparation of substituted amido phthalocyanines having the general formula (I): MPc-(CONR1R2)n, via the reaction of a phthalocyanine carboxamide having the formula MPc (CONH2)x wherein Pc is a Phthalocyanine ring; M is a hydrogen or a metal capable of forming a metal phthalocyanine such as Mg, Al, Ni, Fe, Zn, Pb, Sn or Cu and x is a number from 0.1 to 4.0, with an amine acid salt denoted by formula (II), wherein R1 and R2 are independently selected from the group consisting of hydrogen; an alkyl group having 1-20 carbons; a cyclic alkyl group; an aryl group; an arylakyl having 1- 20 carbons; an alcohol group having 2-20 carbons; an alkyl amino alkyl group; an aliphatic amine having 1-20 carbons; an aliphatic amine acid salt having 1- 20 carbons; polyoxyalylene groups ranging in molecular weight 89-2000; polyoxyalkyleneamines ranging in molecular weight 148-4000; Z is the hydrogen sulphate or the hydrochloride salt of the amine.

L'invention concerne un procédé de préparation d'amidophtalocyanines de formule générale (I): MPc-(CONR?1¿R?2¿)¿n?, qui consiste à faire réagir un carboxamide de phtalocyanine de formule MPc(CONH¿2?)¿x?, Pc représentant un cycle phtalocyanine; M représentant un hydrogène ou un métal capable de former une phtalocyanine, tel que Mg, Al, Ni, Fe, Zn, Pb, Sn ou Cu et x valant 0,1 à 4,0, avec un sel d'acide aminé représenté par la formule (II) dans laquelle R?1¿ et R?2¿ sont choisis séparément dans le groupe constitué d'hydrogène; d'un groupe alkyle possédant 1 à 20 atomes de carbone; d'un groupe alkyle cyclique; d'un groupe aryle; d'un arylalkyle possédant 1 à 20 atomes de carbone; d'un groupe alcool possédant 2 à 20 atomes de carbone; d'un groupe alkyle-aminoalkyle; d'une amine aliphatique possédant 1 à 20 atomes de carbone; d'un sel d'acide aminé aliphatique possédant 1 à 20 atomes de carbone; de groupes polyoxyalkylène dont le poids moléculaire est compris entre 89 et 2 000; de polyoxyalkylènamines dont le poids moléculaire varie entre 148 et 4 000; Z représente sulfate d'hydrogène ou le sel d'hydrochlorure de l'amine.

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