Process for the preparation of tertiary-butyl hydroperoxide

C - Chemistry – Metallurgy – 07 – C

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260/642.9

C07C 409/04 (2006.01)

Patent

CA 1208661

16 A B S T R A C T A PROCESS FOR THE PREPARATION OF TERTIARY-BUTYL HYDROPEROXIDE In the direct oxidation of isobutane with molecular oxygen at moderate isobutane conversion levels in a reaction mixture maintained at a pressure greater than its critical pressure and at a temperature in the range from 140°C to 170°C, the select- ivity of the isobutane conversion to tertiary-butyl hydroperoxide is enhanced with only minimal impact on the reaction rate by controlling the oxygen concentration in the reaction mixture at a level below about 0.1 mol.%.

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