Process for the preparation of tertiary olefines

C - Chemistry – Metallurgy – 07 – C

Patent

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260/639.2, 260/7

C07C 11/02 (2006.01) B01J 29/18 (2006.01) C07C 1/20 (2006.01) C07C 29/10 (2006.01) C07C 31/02 (2006.01)

Patent

CA 1178622

ABSTRACT OF THE DISCLOSURE Process for the preparation of tertiary olefins by catalytic cleavage of their n-alkyl ethers at elevated temperature and with simultaneously recovery of the corresponding n-alkanols, characterized in that the cleavage is carried out in the presence of acidic molecular sieves, which have been activated, if necessary, by a treatment with hydrogen, at temperatures of from 100 to 300°C.

392579

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