Process for the preparation of tertiary olefins

C - Chemistry – Metallurgy – 07 – C

Patent

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Details

260/709.9

C07C 1/20 (2006.01) B01J 21/08 (2006.01) B01J 35/10 (2006.01)

Patent

CA 1117986

ABSTRACT OF THE DISCLOSURE: A process is disclosed for preparing tertiary olefins having a high degree of purity and in good yields, starting from tertiary ethers such as methyl-tert.butyl ether and in which the improvement comprises using an extremely efficient catalyst system which consists of a crystalline silica, having a high specific surface area and which has been modified by an oxide of a metallic cation having an at least partially amphoteric character. Such catalyst may be, if appropriate, accompanied by an alumina-modified silica as an adjuvant co-catalyst.

329429

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