Process for the preparation of tetraalkyl...

C - Chemistry – Metallurgy – 25 – B

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C25B 3/10 (2006.01) C07C 55/00 (2006.01) C07C 67/343 (2006.01) C07C 69/34 (2006.01)

Patent

CA 2241652

Electrolytic hydrodimeric coupling of dialkyl maleates in alkanol solutions containing an alkanol-soluble alkali metal alkoxide/quaternary ammonium tetrafluoroborate mixed supporting electrolyte yields tetraalkyl 1,2,3,4- butanetetracarboxylates.

Cette invention concerne un couplage hydrodimère électrolytique de maléates de dialkyle dans des solutions d'alcanol qui contiennent un électrolyte servant de support à un mélange alcoxyde de métal alcalin soluble dans l'alcanol/tétrafluoroborate d'ammonium quaternaire. Ce couplage permet d'obtenir des tétraalkyle 1,2,3,4-butanetétracarboxylates.

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