Process for the preparation of titanium thio-derivatives

C - Chemistry – Metallurgy – 07 – F

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260/425.7, 260/4

C07F 17/00 (2006.01) C07F 7/28 (2006.01)

Patent

CA 1047516

ABSTRACT OF THE DISCLOSURE: A process for the preparation of titanium thio-deriva- tives of formulae Ti cp2 (SR)2 (Ti cp2 SR)2 wherein cp represents cyclopentadienyl and R represents an alkyl, aryl or cycloalkyl radical, consisting in reacting a titanium compound of formula Ticp2 (CO)2 wherein cp has the aforesaid meanings with a disulfide of the formula S2 R2 wherein R has the aforesaid meanings. The titanium thio-derivatives obtained are useful as polymerization catalysts.

227219

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