Process for the preparation of triiodinated carboxylic...

C - Chemistry – Metallurgy – 07 – C

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C07C 231/10 (2006.01) C07C 235/16 (2006.01) C07C 237/52 (2006.01)

Patent

CA 2755650

The present invention relates to a process for the preparation of given carboxamido compounds, in particular of 2,4,6-triiodoisophthalic acid derivatives, as useful intermediates for the preparation of X-ray contrast media among which is iopamidol. The said process comprises reacting suitable N-sulfinyl intermediate compounds with a commercially available .alpha.-hy-droxyacid or a salt thereof.

La présente invention concerne un procédé de préparation de composés carboxamido donnés, en particulier de dérivés de l'acide 2,4,6-triiodoisophthalique, comme intermédiaires utiles pour la préparation de produits de contraste pour imagerie aux rayons X dont l'iopamidol. Ledit procédé comprend l'étape consistant à faire réagir des composés intermédiaires N-sulfinyle appropriés avec un a-hydroxyacide disponible dans le commerce ou un sel de celui-ci.

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