Process for the preparation of unsaturated alcohols and/or...

C - Chemistry – Metallurgy – 07 – C

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260/493.7, 260/6

C07C 33/03 (2006.01) C07C 29/04 (2006.01) C07C 33/025 (2006.01) C07C 69/145 (2006.01)

Patent

CA 1216591

PROCESS FOR THE PREPARATION OF UNSATURATED ALCOHOLS AND/OR ESTERS THEREOF Abstract of the Disclosure Process for the preparation of unsaturated alcohols and/or esters thereof by reacting conjugated dienes with water and/or aqueous carboxylic acid solutions in the presence of a macroporous acid ion exchanger and suitable solvents. The diene has the general formula I Image (I) in which R1, R2 and R3 are hydrogen or a methyl group and R2 also can represent an aliphatic hydrocarbon radical having 2 to 6 carbon atoms which may contain a double bond which is not in a conjugated position relative to the double bonds of the diene, and preferably R1 and R3 each represent groups CH3 or CH2-CH3. Said diene is reacted in a homogeneous or quasi-homogeneous phase in the presence of said macroporous acid ion exchanger.

419477

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