Process for the production of a mixture of methanol and...

C - Chemistry – Metallurgy – 10 – L

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C10L 1/02 (2006.01) B01J 23/26 (2006.01) B01J 23/80 (2006.01) B01J 23/86 (2006.01) C07C 29/151 (2006.01) C07C 29/153 (2006.01) C07C 29/154 (2006.01)

Patent

CA 1159257

PROCESS FOR THE PRODUCTION OF A MIXTURE OF METHANOL AND HIGHER ALCOHOLS OF "FUEL GRADE" ABSTRACT OF THE DISCLOSURE: A process for the production of a mixture of methanol and higher alcohols of "fuel grade" from CO and H2. To reduce the water content in the mixture coming from the synthesis reactor of the synthesis of the alcohols, the reaction product is cooled down and is fed to a secondary reactor wherein the conversion reaction Image is carried on in conditions near to equilibrium. The further product of reaction is cooled in a more thorough manner so as to obtain a liquid phase constituted by the "fuel grade" mixture of alcohols and a gaseous phase which after the discharge of the inert substances and after elimination of the CO2 is recycled to the synthesis reactor. In the secondary conversion reactor operation is carried out with a temperature comprised between 150°C and 250°C, at a pressure equal to that of the synthesis reactor and in the presence of a copper catalyst.

377761

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