C - Chemistry – Metallurgy – 07 – D
Patent
C - Chemistry, Metallurgy
07
D
260/391.3, 260/2
C07D 223/10 (2006.01) B01J 29/84 (2006.01) B01J 29/86 (2006.01) C07D 201/04 (2006.01)
Patent
CA 1283102
-258- PROCESS FOR THE PRODUCTION OF AMIDES ABSTRACT Oximes can be converted to the corresponding amides by contacting the oximes with a non-zeolitic molecular sieve, which has in its calcined form an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20°C. The process is especially useful for the conversion of cyclohexanone oxime to caprolactam. The non-zeolitic molecular sieves can achieve improved conversion rates and selectivities as compared with conventional zeolite catalysts for the reaction. D-15089
540212
Olson Kurt D.
Sim & Mcburney
Union Carbide Corporation
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