Process for the production of carboxylic acid anhydrides

C - Chemistry – Metallurgy – 07 – C

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C07C 51/56 (2006.01)

Patent

CA 2052632

Case 7623(2) ABSTRACT OF THE DISCLOSURE PROCESS FOR THE PRODUCTION OF CARBOXYLIC ACID ANHYDRIDES The solubility and stability of rhodium catalysts in rhodium-catalysed carbonylation of alkyl estsrs or alkyl ethers under substantially anhydrous conditions to produce carboxylic acid anhydrides is improved by the use of co-promoters selected from the group: 1,3-dialkyl-4-methylimidazolium iodide; 1,3-dialkyl-4-ethylimidazolium iodide; 1,3-dialky1-4-n-propylimidazolium iodide; 1,3-dialkyl-4-isopropylimidazolium iodide; 1,3-dialkyl-4-n-butylimidazolium iodide 1,3-dialkyl-4-sec-butylimidazolium iodide 1,3-dialkyl-4-tert-butylimidazolium iodide; 1,3-dialkyl-2,4,5-trimethylimidazolium iodide and mixtures thereof where the alkyl groups are independently C1 to C20 alkyl.

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