Process for the production of chlorine dioxide

C - Chemistry – Metallurgy – 25 – B

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C25B 1/26 (2006.01) C01B 7/03 (2006.01) C01B 11/02 (2006.01)

Patent

CA 2086454

A process for the production of chlorine dioxide by reacting at least one of chloric acid and an alkali metal chlorate, and hydrogen peroxide as the reducing agent in such proportions that chlorine dioxide is produced in a reaction medium. A mixture comprising chlorine dioxide and oxygen is withdrawn from the reaction medium. Urea and/or one or more phosphonic acid based complexing agents are added to the reaction medium. The stabilizer is added in an amount of 0.01 - 5 weight % and serves to increase the reaction rate.

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